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Potassium-Argon Dating Potassium-Argon dating is the only viable technique for dating very old archaeological materials. Geologists have used this method to date rocks as much as 4 billion years old. It is based on the fact that some of the radioactive isotope of Potassium, Potassium K ,decays to the gas Argon as Argon Ar By comparing the proportion of K to Ar in a sample of volcanic rock, and knowing the decay rate of K, the date that the rock formed can be determined. How Does the Reaction Work? Potassium K is one of the most abundant elements in the Earth's crust 2. One out of every 10, Potassium atoms is radioactive Potassium K

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The Editors of Encyclopaedia Britannica Encyclopaedia Britannica's editors oversee subject areas in which they have extensive knowledge, whether from years of experience gained by working on that content or via study for an advanced degree See Article History. Read More on This Topic. This is possible in potassium-argon K-Ar dating, for example, because most minerals do not take argon into their structures initially Learn More in these related Britannica articles:.

This is possible in potassium-argon K-Ar dating, for example, because most minerals do not take argon into their structures initially.

In rubidium-strontium dating, micas exclude strontium when they form but accept much rubidium.

In uranium-lead U-Pb dating of zircon, the zircon is found to exclude initial lead. The radioactive decay scheme involving the breakdown of potassium of mass 40 40 K to argon gas of mass 40 40 Ar formed the basis of the first widely used isotopic dating method.

Since radiogenic argon was first detected in by the American geophysicist. Potassium-argon dating has made it possible to establish that the earliest remains of man and his artifacts in East Africa go back at least 2, years, and probably further.

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The geomagnetic polarity time scale was calibrated largely using K-Ar dating. The 40 K isotope is radioactive; it decays with a half-life of 1.

### A-Z of Archaeology: 'K - K-Ar Dating' (Potassium - Argon Dating)

Conversion to stable 40 Ca occurs via electron emission beta decay in Conversion to stable 40 Ar occurs via electron capture in the remaining Argon, being a noble gasis a minor component of most rock samples of geochronological interest: It does not bind with other atoms in a crystal lattice.

When 40 K decays to 40 Ar ; the atom typically remains trapped within the lattice because it is larger than the spaces between the other atoms in a mineral crystal.

Entrained argon - diffused argon that fails to escape from the magma - may again become trapped in crystals when magma cools to become solid rock again. After the recrystallization of magma, more 40 K will decay and 40 Ar will again accumulate, along with the entrained argon atoms, trapped in the mineral crystals. Measurement of the quantity of 40 Ar atoms is used to compute the amount of time that has passed since a rock sample has solidified.

Jan 31, The potassium-argon (K-Ar) isotopic dating method is especially useful for determining the age of lavas. Developed in the s, it was important in developing the theory of plate tectonics and in calibrating the geologic time scale. The potassium-argon dating method has been used to measure a wide variety of ages. The potassium-argon age of some meteorites is as old as 4, years, and volcanic rocks as young as 20, years old have been measured by this method.

Despite 40 Ca being the favored daughter nuclide, it is rarely useful in dating because calcium is so common in the crust, with 40 Ca being the most abundant isotope. Thus, the amount of calcium originally present is not known and can vary enough to confound measurements of the small increases produced by radioactive decay.

The ratio of the amount of 40 Ar to that of 40 K is directly related to the time elapsed since the rock was cool enough to trap the Ar by the equation. The scale factor 0.

# Potassium argon method of dating

In practice, each of these values may be expressed as a proportion of the total potassium present, as only relative, not absolute, quantities are required. To obtain the content ratio of isotopes 40 Ar to 40 K in a rock or mineral, the amount of Ar is measured by mass spectrometry of the gases released when a rock sample is volatilized in vacuum.

The potassium is quantified by flame photometry or atomic absorption spectroscopy. The amount of 40 K is rarely measured directly.

Potassium-Argon Dating Potassium-Argon dating is the only viable technique for dating very old archaeological materials. Geologists have used this method to date rocks as much as 4 billion years old. It is based on the fact that some of the radioactive isotope of Potassium, Potassium (K),decays to the gas Argon as Argon (Ar). Potassium-Argon Dating. Potassium-Argon dating has the advantage that the argon is an inert gas that does not react chemically and would not be expected to be included in the solidification of a rock, so any found inside a rock is very likely the result of radioactive decay of potassium. Since the argon will escape if the rock is melted, the dates obtained are to the last molten time for the rock. How potassium-argon dating works Published: 24 June (GMT+10) Photo Wikipedia by Tas Walker. One of the most widely used dating methods is the potassium-argon method, which has been applied to 'dating' rocks for decades, especially igneous rocks that have solidified from molten magma.

The amount of 40 Ar is also measured to assess how much of the total argon is atmospheric in origin. Both flame photometry and mass spectrometry are destructive tests, so particular care is needed to ensure that the aliquots used are truly representative of the sample.

Ar-Ar dating is a similar technique which compares isotopic ratios from the same portion of the sample to avoid this problem. Due to the long half-life of 40 Kthe technique is most applicable for dating minerals and rocks more thanyears old. For shorter timescales, it is unlikely that enough 40 Ar will have had time to accumulate in order to be accurately measurable.

K-Ar dating was instrumental in the development of the geomagnetic polarity time scale.